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Researchers at Rensselaer Polytechnic Institute have discovered the origins of nanorod diameter, demonstrating that the competition and collaboration among various mechanisms of atomic transport hold the key to nanorod size. The researchers say it is the first study to identify the fundamental reasons why nearly all nanorods have a diameter on the order of 100 nanometres.
"Scientists have been fabricating nanorods for decades, but no one has ever answered the question, ‘Why is that possible?'" said Hanchen Huang, professor in Rensselaer's Department of Mechanical, Aerospace, and Nuclear Engineering, who led the study. "We have used computer modelling to identify, for the first time, the fundamental reasons behind nanorod diameter. With this new understanding, we should be able to better control nanorods, and therefore design better devices."
Results of the study, titled "A characteristic length scale of nanorods diameter during growth," were recently published in the journal Physical Review Letters.
When fabricating nanorods, atoms are released at an oblique angle onto a surface, and the atoms accumulate and grow into nanorods about 100 nanometres in diameter. A nanometre is one billionth of a meter in length.
The accumulating atoms form small layers. After being deposited onto a layer, it takes varying amounts of energy for atoms to travel or "step" downward to a lower layer, depending on the step height. In a previous study, Huang and colleagues calculated and identified these precise energy requirements. As a result, the researchers discovered the fundamental reason nanorods grow tall: as atoms are unable to step down to the next lowest layer, they begin to stack up and grow higher.
It is the cooperation and competition of atoms in this process of multi-layer diffusion that accounts for the fundamental diameter of nanorods, Huang shows in the new study. The rate at which atoms are being deposited onto the surface, as well as the temperature of the surface, also factor into the equation.
"Surface steps are effective in slowing down the mass transport of surface atoms, and aggregated surface steps are even more effective," Huang said. "This extra effectiveness makes the diameter of nanorods around 100 nanometres; without it the diameter would go up to 10 microns."
Beyond advancing scientific theory, Huang said the discovery could have implications for developing photonic materials and fuel cell catalysts.
Huang co-authored the paper with Rensselaer Research Scientist Longguang Zhou.
Funding for this research was provided by the U.S. Department of Energy Office of Basic Energy Science.